Compositions and methods relating to freezer-to-oven doughs

ABSTRACT

Described are dough compositions and methods, wherein the dough composition is prepared using a metabolized portion of dough comprising bubbles, metabolically active yeast, and developed dough matrix, combined with non-metabolized yeast, and wherein the dough composition preferably has useful properties such as yeast-leavened freezer-to-oven capabilities, without the need for chemical leavening agents or modified atmosphere packaging.

FIELD OF THE INVENTION

The invention is generally directed to compositions and methods usefulfor producing dough compositions and baked dough products. These includemethods and compositions useful for producing “freezer-to-oven,” “FTO”doughs that can be stored frozen without proofing and that can be bakedwithout being thawed or proofed. Preferred embodiments can be packagedwithout modified atmosphere packaging, and do not require chemicalleavening agents.

BACKGROUND

Frozen doughs are desirable for commercial and home baking because theyminimize preparation time and are easy to use. Such ready-to-bake doughsshould be storage stable when frozen and should provide baked productshaving good organoleptic qualities and aesthetic appeal. Examples offrozen doughs include those described in U.S. Pat. Nos. 4,847,104;4,966,778; 5,447,738; 5,560,946; 5,254,351; and in PCT Application WO96/34530.

Frozen doughs come in a variety of different product types, e.g., basedon the steps required to prepare a baked product from the dough. Asbackground, dough products can require expansion during baking, and canalso require proofing, i.e., allowing the dough to sit to allow yeast toproduce carbon dioxide that expands the dough prior to and duringbaking. Many frozen doughs operate on this principle, with yeast as aleavening agent. When using typical yeast-leavened frozen doughs, aconsumer will thaw the bread out of the freezer, allow the bread to sit(i.e., proof) for a time sufficient for the bread to produce carbondioxide that will expand during baking, and then, finally, be the bread.The steps of thawing and proofing can be very time-consuming. Whenpreparing these types of frozen doughs, designed for preparation by aconsumer by thawing, proofing, and then baking, it is generallypreferred to avoid allowing yeast to metabolize prior to freezing, toenhance storage stability and to allow substantial leavening duringbaking.

Other types of frozen doughs are designed to remove or reduce the amountof tune a consumer spends between freezer and oven. Some frozen doughproducts are sold “pre-proofed,” which means that the dough is allowedto rise before freezing. Preproofed doughs have several drawbacks.Pre-proofed doughs can be expensive because a proofing step must beperformed during the manufacturing process, and, such doughs can requirea significant amount of storage space. Moreover, pre-proofed doughs canbe susceptible to damage by temperature fluctuations, the formation ofice crystals, and mechanical stresses.

As another alternative, some frozen doughs are not pre proofed butinclude chemical leavening agents and do not require a proofing step.These dough compositions use chemical leavening agents instead of yeast.The chemical leavening agent operates differently from yeast. Whileyeast requires time after thawing and prior to baking, for sitting atambient temperature to produce carbon dioxide, a chemical leaveningagent produces a gas at baking temperature, during baking, to expand thedough. The dough may or may not require thawing between the freezer andoven.

Some types of frozen dough products, especially pr-proofed,yeast-leavened, frozen dough products, are sometimes sold inmodified-atmosphere packaging. The packaging can include an inert gassuch as nitrogen or carbon dioxide to prevent oxidation of the frozendough and to maintain a high concentration of carbon dioxide in thefrozen dough to loss of carbon dioxide from the dough during storage andfor expansion of the dough during baking. Modified atmosphere packaginghas drawbacks such as added cost and complexity.

There is a continuing need to provide new methods and compositionsuseful in producing frozen dough products. Especially desirable would bemethods and compositions capable of producing a frozen dough compositionthat can be stored frozen without first being proofed or partiallybaked, especially that can also provide a desirable baked dough productwithout being thawed or proofed after freezing and before being baked.Most preferably, either or both of these goals might desirably be metwithout the need for chemical leaveners or modified atmospherepackaging.

SUMMARY OF THE INVENTION

The embodiments of the present invention described below are notintended to be exhaustive or to limit the invention to the precise formsdisclosed in the following detailed description. Rather, the embodimentsare chosen and described so that others skilled in the art mayappreciate and understand the principles and practices of the presentinvention.

Generally, the invention relates to the discovery that selection andoptimizing of ingredients of a dough composition, also in combinationwith selection of processing steps and conditions, allows otherwisestandard dough ingredients to be processed into a frozen doughcomposition having freezer-to-oven convenience, without the necessityfor chemical leavening agents, partial baking before freezing,pre-proofing before baking, or the use of modified atmosphere packaging.

The invention involves techniques of producing a frozen doughcomposition that exhibits these useful properties, including: combininggeneral dough ingredients; allowing for metabolizing of a portion ofyeast of the total dough composition to produce bubbles in a developeddough matrix; maintaining the bubbles through processing to be presentat baking; and allowing for the presence of non-metabolized yeast in thedough composition, especially when frozen and at baking. Allowing aportion of the total amount of yeast to metabolize produces nucleationsites, e.g., bubbles, in the dough composition. The bubbles are retainedby the developed dough composition into baking, to expand during bakingto leaven the dough. Yeast which has not been allowed to metabolizeprior to baking is also present for metabolization and leavening uponbaking. The dough, including the bubbles and non-metabolized yeast, canbe directly frozen and baked without thawing. The combination of bubblesand non-metabolized yeast combine their leavening effects during bakingto leaven the dough composition to a desired baked specific volume. Thedeveloped dough composition matrix can withstand freezing whilemaintaining the bubbles.

Specific ingredients, processing steps, and features of a doughcomposition that can be selected to achieve the described performanceinclude those that will provide the following.

Ingredients to provide a strengthened or developed gluten matrix ornetwork dough matrix that can maintain bubbles before and duringfreezing. Flour may contribute toward a developed matrix, and a doughcomposition may contain ordinary flour, high protein flour, or both,optionally with added gluten to strengthen and stabilize the doughmatrix to maintain bubbles through processing and into baking, where thebubbles can be available to leaven the dough. Preferred developed doughcompositions may be produced by allowing yeast to metabolize duringprocessing, e.g., using a rest or cooling step, such as a discretefloor-time resting or cooling step, by using a pre-fermented or restedsponge for a time sufficient to develop gluten, resting or cooling timebetween processing of the dough composition after mixing but beforefreezing, such as between lamination steps, or another step that allowsdevelopment of gluten; through the use of strengtheners (e.g.,transglutaminase or others); or by including re-work dough compositionthat has been processed for a time sufficient to allow the matrix todevelop.

-   -   Nucleation sites, e.g., bubbles, which contain gas that will        leaven the dough composition during baking. Bubbles can be        introduced in a pre-fermented sponge, in a re-work composition,        or using processing steps such as mixing or post-mixing        processing such as folding, laminating, lapping, or another        method of incorporating gas or bubbles into a dough composition.        The type and amount of yeast included in the metabolized dough        portion can be selected to become metabolically active during        processing to produce a useful amount of bubbles that can be        retained trough processing and frozen storage for leavening        during baking.    -   An amount of non-metabolically active yeast. Yeast is included        in the dough composition, at least a portion of which will        non-metabolically active into and through frozen storage for        availability during baking, to leaven the dough composition.

These inventive dough compositions can be prepared by any method orcombination of steps that are identified and selected, in combinationwith dough ingredients, to achieve performance properties describedherein. The invention identifies certain exemplary methods andcompositions for preparing the described dough compositions and bakeddough products. One embodiment of a method of the invention, generallystated, involves producing a pre-metabolized dough sponge that includesmetabolized yeast, bubbles, and gaseous yeast metabolites (e.g., carbondioxide) and combining the pre-fermented sponge with additional doughingredients including non-metabolized yeast to produce a doughcomposition. The combined dough composition includes bubbles,metabolically active yeast, non-metabolically active yeast, and adeveloped dough matrix. The dough composition can optionally andpreferably not be partially baked or proofed, but can be frozen andbaked without intermediate steps of thawing or proofing to a yeastleavened dough product, also preferably without the need for chemicalleavening agents.

A preferred dough composition sponge can include a portion of theingredients that go into the overall dough composition, preferablyincluding water, flour, and yeast in an amount that is only a portion oftotal amount yeast to be used in the dough The sponge can be fermentedor “pre-fermented” to allow the included portion of yeast to becomemetabolically active and produce carbon dioxide, which takes the form ofbubbles and which becomes absorbed in the water. The bubbles aremaintained in the dough composition and are effective later asnucleating sites for carbon dioxide and water vapor, during baking, toexpand and leaven the dough composition. The pre-fermenting step alsodevelops and strengthens the dough composition, giving visoelasticproperties that allow the sponge and dough composition to expand withoutbreaking. After fermenting the sponge, additional dough ingredients canbe added to the sponge to produce a dough composition that may beprocessed in any desired manner. The additional dough indents mayinclude an additional portion of yeast, which is non-metabolicallyactive. Such later-added yeast can be maintained through processing andin the frozen dough composition in a non-metabolically active state tobe activated for leavening during baking. The additional ingredients canpreferably be added such that the bubbles of the sponge are maintainedand remain in the dough composition. The bubbles are also preferablymaintained through further processing so that when the dough compositionis baked, bubbles of gas cause the bread to expand as does the gasproduction from the previously non-metabolically active yeast.

An alternative embodiment of the invention, generally stated, involvesproviding (instead of a pre-fermented sponge dough composition) anydifferent dough composition that contains dough ingredients such asflour, water, and yeast, and that also includes metabolically activeyeast, a developed dough matrix, and bubbles. An example of such a doughcomposition is dough composition that is removed from dough processingat a point down-line from a mixing step in a commercial doughcomposition manufacturing system, often referred to as “recycle” or“re-work.” Such dough composition includes standard dough ingredients,bubbles, carbon dioxide, metabolically active yeast, and developed doughmatrix. Any other dough composition meeting this description could alsobe used in place of sponge or “re-work” dough. The re-work dough can becombined with additional dough ingredients to produce a doughcomposition that includes bubbles, metabolically active yeast,non-metabolically active yeast, and a developed dough matrix. The doughcomposition can optionally and preferably not be partially baked, andcan be frozen and baked without intermediate steps of thawing, proofing,or partially baking, and preferably without the need for chemicalleavening agents or modified atmospheric packaging.

In preferred embodiments, the invention relates to “un-proofed”freezer-to-oven (“FTO”) frozen dough products, which means frozen doughproducts that can be baked without thawing or proofing, as well asmethods and compositions useful in preparing such FTO dough products.The preferred FTO compositions can be baked without the need for one ormore steps of pre-proofing the dough composition prior to freezing,partially baking the dough composition prior to freezing, thawing thefrozen dough composition between freezing and baking, or proofing thedough composition between freezing and baking. The dough composition canbe capable of substantial expansion upon cooking, thereby producing acooked, yeast-leavened dough product with excellent visual andorganoleptic properties. Preferably, the dough composition can bepackaged and frozen in conventional packaging, which does not contain amodified atmosphere such as a concentration of inert gas or carbondioxide.

Preferred dough compositions of the invention can be un-proofed beforebeing frozen and before being baked and can have a raw specific volumeof between about 0.9 cc/g and about 1.5 cc/g, preferably between about 1cc/g and about 1.3 cc/g, prior to freezing.

A preferred dough composition of the invention can typically be shelfstable for between about 3 months and about 5 months at freezingtemperatures.

The inventive methods and compositions, with their advantageous FTPcapabilities, can be used to prepare all types of frozen doughcompositions and dough-type products such as loaf bread; bread rolls;bread sticks; pizza crusts; rolls, including cinnamon rolls, sweetrolls; laminated dough products such as Danishes, croissants, etc.;filled dough products and the like.

The invention allows the production of dough compositions that exhibitone or more, most preferably all, of the following advantages: noproofing, either before or after freezing or before baking; no thaw Stepbetween freezing and baking; no modified atmosphere packaging; andfreeze-thaw tolerance. Fully yeast-leavened compositions of theinvention can also exhibit advantages in comparison to chemicallyleavened FTO dough products, because such yeast-leavened doughcompositions naturally exude a yeast-leavened aroma, and because they donot sir from limitation of chemically leavened products such as withtaste and they also do not react until heated, unlike yeast.

In one embodiment of the present invention, a method of preparing anunproofed dough composition capable of being frozen and baked withoutthawing to create a yeast-leavened baked dough product is described andincludes the steps of initially providing a set of ingredients includingat least yeast, water, and flour; then combining and processing theindents in combination with additional dough ingredients to produce adough composition, the combining and processing including the steps ofallowing a portion of the yeast to actively ferment a portion of theingredients; next developing the dough composition; then generatingbubbles in the developed dough composition; providing non-metabolicallyactive yeast in the dough composition; then finally the combination ofbubbles, developed dough composition, and non-metabolically activeyeast, results in an unproofed dough composition capable of being frozenwithout partially baking, and baked without thawing, to create ayeast-leavened baked dough product.

In a still further embodiment of the present invention, a method ofmaking an unproofed dough composition is described and includes thesteps of initially providing a metabolized dough portion comprisingmetabolically-active yeast, bubbles, and developed dough matrix; thencombining the metabolized dough portion with additional doughingredients including non-metabolically active yeast, to form a doughcomposition that contains bubbles in developed dough matrix and thatcontains non-metabolically active yeast. The unproofed dough compositionproduced in accordance with the above method can be frozen and bakedwithout thawing or proofing to produce a yeast-leavened baked doughproduct.

In yet a still further embodiment, a frozen unproofed dough product isdescribed and includes a dough composition, having a portion ofmetabolized dough composition that includes water, flour,metabolically-activated yeast, bubbles, and developed dough compositionmatrix. The dough composition is then combined with additional doughingredients that include non-metabolically-active yeast. The doughcomposition is packaged in non-modified atmosphere packaging. Theunproofed dough composition of the present invention can be bakedwithout thawing to produce a yeast-leavened baked dough product.

A laminated dough composition is also described that includesalternating dough composition layers and shortening layers, wherein thedough composition layers include transglutaminase.

A method of making a laminated dough composition is described andincludes the steps of initially providing a dough composition comprisingwater, flour, yeast, and transglutaminase, and then processing the doughcomposition by lapping the dough composition to form multiple layers ofdough composition and shortening to provide a developed dough matrix.

An unproofed dough composition is also depicted in other embodiments ofthe present invention and includes an amount of metabolically activeyeast, an amount of non-metabolically active yeast, bubbles, and adeveloped dough matrix. The combination of bubbles, developed doughmatrix, and non-metabolically active yeast result in an unproofed doughcomposition capable of being frozen and baked without thawing to ayeast-leavened baked dough product.

A still flier exemplary embodiment of the present invention relates to acontinuous method of preparing an unproofed dough composition that canbe frozen and then baked without thawing to produce a yeast-leavenedbaked dough product which includes the steps of initially providing adough sponge comprising water, flour, yeast, and yeast nutrient; thenpre-fermenting the dough sponge to produce a pre-metabolized doughsponge comprising metabolically active yeast and bubbles in astrengthened sponge matrix. Next, the pre-fermented sponge is combinedwith additional dough ingredients including non-metabolically activeyeast. The dough composition is processed to create a dough compositioncomprising metabolically active yeast, bubbles, non-metabolically activeyeast, and a developed dough matrix, which can be frozen and then bakedwithout thawing to a yeast-leavened baked dough product, wherein theprocessing produces rework dough removed from the dough composition, there-work dough comprising metabolically-active yeast, bubbles, and adeveloped dough matrix. Finally, the re-work dough with the doughcomposition at a processing step upstream from where the rework doughwas removed, to produce a dough composition comprising metabolicallyactive yeast, bubbles, non-metabolically active yeast, and a developeddough mat wherein that combined dough composition comprising the re-workdough can be frozen and then baked without thawing to produce ayeast-leavened baked dough product.

As used herein, the following terms represent the given meanings.

“Dough sponge” or “sponge” means a composition containing at leastwater, four, yeast, and optionally yeast nutrient and optional gluten,and optionally other dough ingredients such as sugar, salt, shorting,flavorings, etc., particularly when the ingredients are combined inamounts having significantly more water than a standard doughcomposition.

“Ferment” or “metabolize” means to produce or allow changes in a doughcomposition or sponge brought about by the metabolic action of yeastenzymes that function to produce metabolites such as carbon dioxide,ethanol, etc., in a dough composition or sponge, and also to develop thedough composition or dough composition sponge; “pre-ferment” is usedspecifically to refer to fermenting a dough sponge.

“Proofing” refers to a generally final) step before baking or freezing adough composition, wherein a dough composition is given time to allowyeast to metabolize and produce gaseous metabolites, generally includingcarbon dioxide, that will expand the dough composition to a desiredvolume and optionally to a desired shape.

“Yeast-leavened” refers to dough compositions that are leavenedprimarily due to the production of gaseous metabolites by yeast;chemical leavening agents may be present, but in a minor amounts,preferably less than 10 percent by weight chemical leavening agent basedon the total weight of leavening agent (yeast and chemical leaven agent)or may not be present at all. As used herein with respect to theinvention, yeast-leavened refers also to a dough product that isleavened to a degree that is understood to be useful for typical andstandard leavened dough products, for example to a baked specific volumeof at least 2 or 2.5 cubic centimeters per gram (cc/g), preferably up to4 or 5 or 6 cc/g, or even a higher baked specific volume.

“Chemical leavening agent” or “CLA” is used consistently with theunderstood meaning of the term in the dough and baking arts; the termrefers to chemical materials used as alternatives to yeast leaveningagents for leavening dough products, generally by reaction of twocomplementary ingredients, e.g., an acid and a complementary base, toproduce a gaseous reaction product that leavens a dough product; theterm does not include compounds such as water, carbon dioxide, orethanol, otherwise normally present in yeast-leavened dough compositionsor produced as yeast metabolites.

These, as well as other objects and advantages of this invention, willbe more completely understood and appreciated by referring to thefollowing more detailed description of the presently preferred exemplaryembodiments of the invention.

DETAILED DESCRIPTION

The present invention is now illustrated in greater detail by way of thefollowing detailed description, but it should be understood that thepresent invention is not to be construed as being limited thereto.

Dough compositions of the invention can be prepared by selectingingredients (including ingredient compositions and amounts) andprocessing techniques used to prepare a dough composition, to produce afrozen dough composition that has convenient qualities such as one ormore of “freezer-to-oven” capabilities and freeze thaw stability,preferably without the need for pre-proofing, partially baking, chemicalleavening agents, or modified atmosphere packaging.

The invention specifically involves techniques of producing a frozendough composition that include: combining select dough ingredients;allowing for metabolization by a portion of yeast in a doughcomposition, to provide bubbles and a developed dough matrix; processingto allow the bubbles to be maintained in the dough compositionthroughout subsequent processing steps and to freezing and baking; andproviding or allowing for the presence of yeast that are notmetabolically active (during free and baking). Metabolizing activity byan the total amount of yeast of a dough composition produces nucleationsites, e.g., bubbles, in a dough composition and a developed doughmatrix. The bubbles are maintained by the developed dough matrix duringprocessing and are available to expand during baking to leaven thedough. Non-metabolizing yeast is also present for metabolization duringbaking and an additional contribution to leavening. The dough, includingthe bubbles and non-metabolizing yeast, can be directly frozen and bakedwithout thawing.

The dough composition can be produced by providing a portion of doughcomposition that contains metabolizing yeast (a “metabolized dough”composition or “portion”) and combining metabolized portion withadditional ingredients including non-metabolizing yeast.

The metabolized dough composition contains dough ingredients such asflour, water, sugar, yeast optional gluten, and optional yeast food, andis processed to produce bubbles, metabolically active and yeastmetabolites, and a strengthened or developed dough matrix.

Bubbles can be produced in a metabolized dough portion by yeastmetabolites such as carbon dioxide forming in the dough matrix. Bubblescan also be produced by processing steps including mixing, lapping,sheeting, or other steps that entrap gas in a dough composition.

A “developed” dough or dough matrix refers to a dough or dough spongecomposition or matrix, etc., with a woven alignment of gluten proteinstrands. A developed dough according to the invention can maintainbubbles in a dough portion, matrix, or composition, etc., through mixingand subsequent processing and into baking, where the bubbles can beavailable to leaven the dough composition.

Ingredients used to provide a developed dough composition include flour,optionally high protein flour, and an optional strengthener e.g.,gluten, transglutaminase, and others. Flour to contribute toward adeveloped matrix may be ordinary flour, high protein flour, or acombination of these. A developed dough composition can be produced byknown methods that align protein molecules and allow a strengtheningreaction between dough ingredients. Protein molecule alignment can occurdu mixing steps or subsequent handling. Strengthening reactions canoccur by allowing yeast to metabolize, e.g., during processing using arest or cooling step, e.g., as occurs in a dough composition sponge thatis pre-fermented or rested for a time sufficient to develop gluten, asis occurs in a re-work dough composition that has been processed for atime sufficient to allow the dough composition to develop, or can occurduring other processing steps, resting steps, or floor time. Developinga dough composition can also be facilitated and accomplished by use of astrengthener, including gluten, transglutaminase and others known andavailable in the dough and baking arts such as chemical and enzymaticoxidants such as azodicarbonamide and glucose oxidase.

As is discussed in more detail below, two examples of metabolized doughportions include dough composition sponge and re-work dough composition.

Sponge Composition as Metabolized Portion

One important embodiment of the invention relates to methods andcompositions involving a metabolized portion of dough composition in theform of a dough composition sponge (“sponge”). In general, according tothis embodiment, dough compositions of the invention can be prepared byproviding a pre-fermented sponge and adding additional dough ingredientsto that sponge, including non-metabolically active yeast. A liquidpre-ferment step, i.e., a step of pre-fermenting certain doughingredients in the form of a sponge, can provide a sponge comprising awell developed, extensible sponge matrix containing water, flour, and aportion of the yeast to be used in the overall dough composition. Thatportion of yeast is metabolically active during the pre-fermenting stepand produces bubbles of carbon dioxide. The sponge takes the form of adeveloped sponge matrix being interrupted by a large amount of verysmall bubbles containing carbon dioxide and water vapor. Upon combiningthis sponge width the balance of dough ingredients, the bubbles,stabilized by the developed gluten, are effectively maintained into thefinished dough composition. Non-metabolically active yeast is added, atleast a portion of which does not become metabolically active untillater, during baking. During baking, the portion of the yeast that wasnot metabolically active becomes metabolically active to producemetabolites including carbon dioxide. The bubbles serve as nucleatingsites for carbon dioxide and water vapor expansion during baking. Thisproduces expansion without the need for proofing. A strengthener such asgluten, included in a relatively high amount (3 to 6% by weight) in thedough composition, can strengthen the dough composition matrix andenhance the gas holding capacity of the dough. Also, a relatively highamount of yeast (4 to 6% by weight) in the dough composition can producelarge amounts of bubbles for nucleation and can contribute to carbondioxide saturation during processing and oven spring upon baking.

A dough sponge can be prepared by combining ingredients including atleast flour, yeast, and water, and optionally other ingredients such asgluten and a yeast nutrient. These ingredients are combined in anacceptable manner to produce a sponge.

Preferably, the sponge can include a grain constituent (e.g., flour)that contributes to the structure of the sponge and ultimately to thestructures of the dough composition and baked dough product. Wheat flouris a grain constituent that is frequently used in baked goods. Suitableflours include hard wheat winter and spring flours with protein rangesof from about 10 weight percent to about 16 weight percent protein,based on the weight of the flour. A high protein flour (containingbetween about 12 and about 16 weight percent protein) can be preferred,because proteins facilitate conditioning and strengthening of thesponge. Although less referred, soft wheat flour or lower protein flourscan also be used.

The sponge typically includes an amount of flour effective to providedesired sponge structure and consistency, i.e., structure andconsistency that allow for fermentation of yeast, expansion of thesponge, and formation and retention of bubbles. The amount of flourshould not be so great that the sponge is dry and loses its ability toexpand. Yet the amount of flour should not be so low that the sponge haslittle strength or cohesive property, or does not have an ability tomaintain a desired form, e.g., maintain bubbles formed within a spongematrix, or a desired shape. Exemplary amounts of flour in a spongecomposition can be in amounts in the range between about 36 weightpercent and about 56 weight percent flour based on the weight of thesponge, preferably between about 41 weight percent and about 51 weightpercent, and more preferably between about 43 weight percent and about48 weight percent. These amounts are based on flour having about 13weight percent to about 15 weight percent moisture, about 12 weightpercent to about 14 weight percent wheat protein, and about 0.4 weightpercent to about 0.6 weight percent ash based on the amount of flour.One of ordinary skill having read this specification will understandthat amounts of flour suitable for use with such a sponge can varydepending on characteristics of the flour used, as well as the amountsand types of other ingredients, e.g., the amount and properties ofgluten or strengthener in the sponge.

Yeast is included in the sponge to produce metabolites, especiallygaseous metabolites such as carbon dioxide. The amount of yeast can beincluded in the sponge can be an amount that will produce a desiredvolume of metabolites which will in turn cause the sponge to producebubbles and to develop and strengthen especially an amount sufficient toalso cause carbon dioxide to be absorbed by water in the sponge, mostpreferably to saturate the water with carbon dioxide. The amount ofyeast included in a sponge is preferably a portion of the total amountof yeast that will be included in the dough composition, i.e., someamount of yeast is added in later processing.

Preferably, the portion of yeast added to the sponge can be in the rangefrom about 0.75 to about 1.75 percent of the total yeast included in thedough composition, more preferably from about 1 to about 1.5 percent ofthe total yeast used in the dough composition. Stated differently, andwhile amounts outside of these exemplary ranges may also be useful, thiscan mean that the sponge contains from about 2.8 to about 6.6 weightpercent yeast based on the total weight of the sponge, preferably fromabout 3.8 to about 5.7 weight percent yeast based on the weight of thesponge; these amounts have been found to be useful for doughcompositions (prepared from the sponge) that include from about 5 toabout 7 weight percent yeast, e.g., about 6 weight percent yeast, basedon the total weight of the overall dough composition.

The preferred type of yeast for the present invention is compressedyeast as opposed to active dried yeast which may produce less thansatisfactory results. Compressed yeast has above 30% solids and isformed by pressing creamed yeast.

A yeast nutrient can optionally be included in the sponge, but is notrequired. A yeast nutrient can be a nutrient that is useful with aparticular yeast, whereby the yeast and its enzymes can metabolize thenutrient to produce metabolites, especially carbon dioxide, and oftenother metabolites such as ethanol. Yeast nutrient is not requiredbecause many flours include sufficient amounts of materials that act asnutrients to allow the yeast to effectively metabolize without additionof separate nutrient. A single example of useful yeast nutrient is aclass of sugars generally known to act as yeast nutrients, includingdextrose.

The amount of yeast nutrient included in a sponge can be any amount thatis useful for the amount of yeast, to produce a desired amount ofmetabolites, as will be understood by a skilled artisan. Examples ofpreferred amounts of yeast nutrient, such as dextrose, in a sponge canbe at least about 3 weight percent based on the weight of the spongeincluding the range from about 2 to about 4 weight percent yeastnutrient (dextrose), based on the weight of the sponge.

The sponge can include a strengthener such as a protein-basedstrengthener, e.g., gluten, or transglutaminase, or other knownstrengtheners, for increasing the strength and extensibility of thesponge. (See the more detailed discussion of strengtheners, infra,“Additional Dough Ingredients.”) The use of a strengthener can increasethe gas-holding capacity of the sponge by allowing the sponge to expandinstead of breaking upon evolution of carbon dioxide by the yeast; i.e.,the strengthener can provide desirable viscoelastic properties. Variousyes of strengtheners may be used, as will be understood by a skilledartisan, with a preferred strengthener being gluten, especially vitalwheat gluten, and another preferred strengthener for certain embodimentsof the invention being transglutaminase.

Generally, a useful amount of gluten can be any amount that willstrengthen the dough, with preferred amounts being in the range from atleast about 3 weight percent of the dough, preferably at least 5 weightpercent of the dough, e.g., from about 4—to about 6 weight percent ofthe sponge.

Generally, a useful amount of transglutaminase as a strengthener can beany amount that will strengthen the sponge.

The sponge includes liquid water in an amount that, with the otheringredients, will produce a sponge having useful properties of a sponge,including useful structure and consistency, i.e., structure andconsistency that allow for fermentation of yeast, expansion, andformation and retention of bubbles. The amount of water in anyparticular sponge composition should be an amount that wets out theingredients and provides a sponge having sufficient strength andcohesion to maintain bubbles formed upon evolution of gaseousmetabolites such as carbon dioxide, e.g., in a closed cell structure ofa sponge matrix contain bubbles of carbon dioxide.

The sponge may include other optional ingredients, as will be understoodby the skilled artisan, including amounts of flavoring, sugar,shortening (oil or plastic) water-binding agent, or additives orpreservatives, as discussed elsewhere in this disclosure. These indentscan be included in the sponge composition in amounts that will produce asponge as described above.

Exemplary Sponge Ingredients WEIGHT PERCENT INGREDIENT USEFUL PREFERREDMORE PREFERRED Flour 30-55 35-50 40-45 Water 30-55 35-50 40-45 Yeast2.8-6.6   3-6.4 3.8.-5.7  Yeast nutrient 0-5 2-5 3-4 (dextrose)

The ingredients of a sponge can be combined in any useful manner thatallows the sponge to be produced and processed to contain bubbles and adeveloped dough matrix. According to the invention, a sponge pre-fermentstep can be performed to produce a dough product that is sufficientlydeveloped, and contains sufficient carbon dioxide and nucleating sites,so that the sponge can be combined with other dough ingredients to forma dough composition that can be frozen, preferably without beingpartially baked, or proofed, and can then be baked directly withouteither a thawing or a proofing step, to produce a baked dough product,also preferably without the need for chemical leavening agents ormodified atmosphere packaging.

Conventional and known methods of preparing sponges will be useful, suchas ordinary dough mixing. Equipment useful for mixing the ingredientswill be readily understood and is commercially available. The order andtiming of addition of the different ingredients is to add doughingredients to the sponge.

As one exemplary set of steps that can be useful to prepare a sponge,water (e.g., at a temperature of between about 60° F. and about 65° F.)and yeast can be mixed until the yeast substantially dissolves. Thewater plus yeast is added to the flour is, and the mixture is mixeduntil the flour is hydrated and a homogenous sponge mixture is obtained.

The sponge can be fermented, or “pre-fermented” by maintaining thesponge at conditions effective to cause yeast fermentation, typicallywhile the sponge is maintained in a stationary and still position. Thesponge can be fermented such the sponge ingredients work together toproduce yeast metabolites such as gaseous carbon dioxide, and otherssuch as ethanol, thereby reacting a highly bubbled and developed glutensponge that can be subsequently processed into a dough composition asdescribed herein.

The temperature and flung of the pre-ferment step can be any that willproduce a useful amount of yeast metabolite, especially to strengthenthe dough composition and to form bubbles containing carbon dioxide (andpreferably water) and to produce carbon dioxide absorbed in the water ofthe sponge. Preferred pa ferment step temperatures can be in the rangefrom about 50 to 100 F, more preferably from about 70 to about 80 F. Insome embodiments, the sponge can be left at room temperature for betweenabout 1 to about 3 hours, preferably from about 1.5 to about 1.75 hours.

The pH of the sponge during pre-fermenting may have an affect on theamount of carbon dioxide produced. While any pH that will produce auseful amount of carbon dioxide can be effective, the solubility ofcarbon dioxide in water may decrease as pH falls below about 6, so a pHin excess of 6 can be preferred, e.g., a pH in the range from about 6 toabout 7.

Also, it can be preferred to control, e.g., minimize, volumetricexpansion of a sponge during pre-fermentation. It can be preferred toproduce and maintain a maximum of closed-cell structure in the sponge. Aclosed cell structure prevents migration of carbon dioxide throughoutthe sponge, and keeps bubble size small. Carbon dioxide can diffuse morerapidly through an open cell sponge structure compared to a closed-cellstructure. Controlling volumetric expansion can prevent some amount ofcell structure breakdown from closed-cell to open cell structures.Additionally, proofed open-ell frozen dough compositions tend to formlarge ice crystals over time, which in turn can dehydrate the gluten andrender the dough composition less extensible.

A goal of fermenting the sponge can be to produce a sponge with a highconcentration of carbon dioxide, including gaseous carbon dioxide andcarbon dioxide dissolved in water, and wherein the sponge also has ahighly developed sponge matrix that will exhibit high viscoelasticityand therefore also exhibit a strong capacity to retain gaseous carbondioxide in the form of bubbles. Additional ingredients are subsequentlyadded to the sponge and processed to produce a dough composition.According to the invention, the bubbles and carbon dioxide present inthe sponge can be maintained through the production of a doughcomposition by addition of more dough ingredients and by subsequentprocessing. This means that a substantial amount, preferably a majorityof, the bubbles and carbon dioxide in the sponge can also be present inthe final (e.g., frozen) dough composition produced from the sponge. Thecarbon dioxide and bubbles later contribute to expansion of the doughcomposition during baking and increase the baked specific volume of thebaked dough product. Overall, the production of carbon dioxide in thedescribed form and amounts in the sponge, by pre-fermentation, incombination with the subsequent addition of non-metabolically activeyeast, can eliminate the need for a proofing step prior to fig orbaking, because carbon dioxide formed bubbles in the sponge remainpresent through subsequent processing to the final dough composition,and the dissolved carbon dioxide (in combination with non-metabolicallyactive yeast) and steam generated upon heating will be present duringbaking in amounts sufficient to expand the dough composition withoutprior proofing, and preferably without the need for chemical leaveningagents.

Re-Work Dough Composition as the Metabolized Portion

Another important embodiment of the invention relates to methods andcompositions involving a metabolized portion of dough that is in theform of recycled or “re-work” dough.

A “recycled” or “work” dough composition refers to a dough compositionthat has been at least partially processed through a dough compositionprocessing line, e.g., mixed, sheeted, laminated or lapped, cut, etc.,and then removed from the processing line, e.g., cut away during shapingor removed due to mis-processing, normally prior to combining the doughcomposition with non-dough ingredients such as fillings or frostings.The re-work can be reintroduced into a dough composition of a same orsimilar formulation at an earlier stage of processing from where it wasremoved. Generally, recycling or re-working dough is a way to reducewaste or improve flavor of a final dough product. As an example, wastedough composition can be removed from a processing line, e.g., cuttingstation, and re-inserted into the same processing line at an earlierstage of processing, typically at a sheeting station. The re-work doughcomposition normally will contain substantially complete doughingredients (e.g., it is not a “sponge”), and, will include a portion ofmetabolically active yeast and therefore developed dough compositionmatrix and bubbles.

Re-work dough composition is typically, according to standard practice,re-added to a dough composition at the sheeting processing step and isnot typically added during mixing of the dough composition. This is forease handling and processing the rework. Also, normally, the use ofre-work is not designed to incorporate bubbles of the re-workcomposition into a dough composition, as described according to thepresent invention. Flavor and lessening of waste is the standardpractice priority. Preferably, according to the invention, the re-workis combined with other dough ingredients, i.e., dough composition, sothat the bubbles are retained by the combined re-work and doughcomposition. This can be accomplished, for example, by adding the reworkduring mixing, so that the gas cells (bubbles) get incorporatedthroughout the dough, and are maintained as bubbles in the developedmatrix of the re-work portion.

Re-work dough can be used as a metabolized portion of dough, asdescribed above, because, similar to a dough sponge, a re-work doughincludes an amount of metabolically active yeast and therefore carbondioxide and bubbles (typically smaller hand the bubbles of a sponge),and developed dough composition matrix.

In general, according to is embodiment, dough compositions of theinvention can be prepared by providing a portion of re-work doughcomposition and adding additional dough ingredients, includingnon-metabolically active yeast, to that re-work portion. (Here, theingredients of the re-work are identical to the ingredients of the doughcomposition from which the re-work was removed, and the “added doughingredients” that are added to the re-work will be the same doughcomposition, but at an earlier stage in processing.) A re-workcomposition generally includes all ingredients of the dough composition,and because it has been at least partially processed over a period oftime, comprises a well-developed, extensible sponge matrix containingbubbles, carbon dioxide, and metabolically-activated yeast. Uponcombining the re-work portion with the balance of dough ingredients, thebubbles, stabilized by the developed gluten, can be effectivelymaintained into the finished dough composition. Non-metabolically activeyeast is present in the combined dough composition, e.g., from thenon-re-work dough composition, which does not become metabolicallyactive until baking. During baking, the portion of yeast that was notmetabolically active becomes metabolically active to produce metabolitesincluding carbon dioxide. The bubbles that are present serve asnucleating sites for carbon dioxide and water vapor expansion duringbaking. This produces expansion without the need for proofing. Gluten,included in relatively high amounts in the dough composition, canstrengthen the dough composition matrix and enhance the gas holdingcapacity of the dough. Also, a relatively high amount of yeast in thedough composition can produce a large amount of bubbles for nucleationand can contribute to carbon dioxide saturation during processing andoven spring upon baking. In the preparation of the Danish in anexemplary embodiment provided herein, the high gluten content decreasedthe extensibility of the dough.

A re-work dough composition can be prepared as a normal doughcomposition, using a full allocation of ingredients of a final doughcomposition (as compared to the portion of ingredients used in preparinga sponge), and by combining the ingredients in a manner typical ofproducing the final dough composition. Ingredients will include standarddough ingredient such as flour, yeast, and water, optional ingredientssuch as gluten and a yeast nutrient, and typically also ingredients suchas shortening (oil or plastic), sugar, flavorings, additives, etc. Theseingredients are combined in an acceptable manner, e.g., by mixing, andprocessed for a time that causes the yeast to metabolize and the doughcomposition to develop, whereupon the recycle portion becomes removedfrom processing and available as “re-work.” The amounts of eachingredient in each of the dough composition and the re-work are the sameamount, which are the amounts used in producing the original andultimately-desired dough composition, because the rework composition hasthe same formulation as the dough composition. Thus, when discussingamounts of ingredients of a re-work portion, they are typically the sameas a desired final dough composition.

The re-work dough portion can include ingredients as described in thesponge, above, for strengthening the dough composition matrix. This mayinclude a grain constituent that contributes to the structure of there-work and ultimately to the structures of the dough composition andbaked dough composition. Suitable flours include hard winter wheat andspring flours with protein ranges of from about 10 weight percent toabout 16 weight percent protein, based on the weight of the flour. Ahigh protein flour (containing between about 12 and about 16 weightpercent protein) can be preferred, because proteins facilitateconditioning and strengthening of the sponge. Although less preferred,soft wheat flour or lower protein flours can also be used.

The re-work typically includes an amount of flour effective to providedesired structure and consistency, i.e., structure and consistency thatallow for fermentation of yeast, expansion, and formation and retentionof bubbles. Exemplary amounts of flour in a re-work composition can bethe same as a final dough composition, e.g., in the range between about35 weight percent and about 60 weight percent flour based on the weightof the dough, preferably between about 40 weight percent and about 55weight percent, and more preferably between about 45 weight percent andabout 55 weight percent. These amounts are based on flour having about13 weight percent to about 15 weight percent moisture, about 12 weightpercent to about 14 weight percent wheat protein, and about 0.4 weightpercent to about 0.6 weight percent ash based on the amount of flour.

Yeast can be included in the re-work in any amount that will produce adesired amount of metabolites, which will in turn cause the re-work todevelop and strengthen. Amounts of yeast normally used in typical doughcompositions can be useful. While amounts outside of these exemplaryranges may also be useful, such amounts can be in the range from about 4to about 8 weight percent yeast based on the total weight of the doughcomposition, preferably from about 5 to about 7 weight percent yeastbased on the total weight of the dough composition.

The type of yeast can be any of a variety of yeasts that are well known,with certain types, such as cake yeast, or compressed yeast with roughly30% solids being preferred.

A yeast nutrient can preferably be included in a standard doughcomposition, and therefore a re-work portion. Yeast nutrient as usedherein includes nutrient such as sugar as well as “yeast foods.” Theamount of yeast nutrient included can be any amount that is appropriatefor the amount of yeast, to produce a desired amount of metabolites, aswill be understood by a skilled artisan.

A dough composition and re-work can optionally and preferably include astrengthener such as a protein-based strengthener, e.g., gluten,transglutaminse, or other known strengtheners, for increasing strengthand extensibility. The use of a strengthener can increase gas-holdingcapacity by allowing expansion instead of breaking upon evolution ofcarbon dioxide by yeast; i.e., the strengthener can provide desirableviscoelastic properties. Various types of strengtheners may be used, aswill be understood by a skilled artisan, with a preferred strengthenerbeing gluten, especially vital wheat gluten, and another preferredstrengthener for certain embodiments of the invention can betransglutaminase.

Generally, a useful amount of gluten can be any amount that willstrengthen the re-work, with preferred amounts being in the range fromat least about 2 weight percent of the dough, preferably at least 6weight percent of the dough.

Generally, a useful amount of transglutaminase as a strengthener can beany amount that will strengthen the re-work.

A dough composition and re-work portion include liquid water in anamount that, with the other ingredients, will produce a re-work anddough composition having useful properties, including useful structureand consistency, i.e., structure and consistency that allow forfermentation of yeast, expansion, and formation and retention ofbubbles. Preferred amounts of water can be at least about 25 weightpercent, e.g., an amount in the range from about 25 to about 40 weightpercent, preferably from about 30 to 35 weight percent, based on theweight of the re-work.

Because the re-work can have the same composition as the final doughcomposition, the re-work can normally include other ingredients,including amounts of flavoring, sugar, shortening (oil or plastic), oradditives or preservatives, as discussed elsewhere in this disclosure.

The ingredients of the re-work can be combined in any useful manner, asused to begin processing of a dough composition, normally by standardmixing and subsequent processing so the dough composition/re-workportion contains bubbles and a developed dough composition matrix. Thisc include steps of mixing, resting, cooling, lapping, cutting sheeting,etc. At some point in the processing of the dough composition, a portionof the in-process dough composition is removed from processing as there-work portion. According to the invention, this re-work portion,containing a developed dough matrix, metabolized yeast, and bubbles, iscombined with dough ingredients, as described herein, somewhere upstreamin the processing of the dough composition.

The use of the re-work portion as a metabolized portion, according tothe invention, works according to the same principles as apply to theuse of a sponge as a metabolized portion. The re-work composition caninclude a relatively high concentration of carbon dioxide, includinggaseous carbon dioxide and carbon dioxide dissolved in the water. There-work composition also has a highly developed matrix that will exhibithigh viscoelasticity and therefore also exhibit a strong capacity toretain gaseous carbon dioxide in the form of bubbles. Additionalingredients are added to the re-work portion, i.e., the re-work iscombined with the in-process dough composition, and the combined doughcomposition is processed to produce a dough composition. According tothe invention, the bubbles and carbon dioxide present in the re-workportion can be maintained through the production of a final doughcomposition. This means that a substantial amount, preferably a majorityof, the bubbles and carbon dioxide in the re-work are also present inthe final dough composition produced from the re-work. The carbondioxide and bubbles later contribute to expansion of the doughcomposition during baking and increase the baked specific volume of thebaked dough product. Overall, the production of carbon dioxide in thedescribed form and amounts in the re-work, in combination with thepresence of non-metabolically active yeast in the dough composition, caneliminate the need for a proofing step prior to freezing or baking,because carbon dioxide and the bubbles formed by the carbon dioxide,remains present through subsequent processing to the dough composition,and the carbon dioxide (in combination with non-metabolically activeyeast) will be present during baking in amounts sufficient to expand thedough composition without prior proofing, and without the need forthawing, preferably without the need for chemical leaveners.

Additional Dough Ingredients

Additional dough ingredients are combined with the metabolized doughportion, to produce a dough composition.

Examples of such additional dough ingredients can include, generally,any one or more of the following: additional flour; water; strengthenersuch as gluten, chemical oxidants, surfactants or transglutaminase,possibly in addition to an amount of strengthener already included in asponge or re-work composition; leavening agents such as yeast;shortening; and other ingredients and additives such as flavorings,sweeteners (e.g., sugar), water-binding agent and others.

The relative amounts of metabolized portion to additional doughingredients can be any amounts of each that will result in a usefuldough composition, as described herein preferably in relative amountsthat will allow freezer-to-oven processing of the dough compositioncombined with useful or desirable final bread properties. Preferably,the amount of metabolized portion as a portion of a total doughcomposition can be an amount that has a measurable effect on the bakedspecific volume of a baked dough composition prepared from the dough,e.g., an amount that causes an increase in the baked specific volume ofa baked dough product prepared from the dough, as compared to a bakedproduct prepared from a dough composition made with identical amounts ofingredients but not prepared using a metabolized portion and processingas described herein. Also preferably, this can be accomplished withoutchemical leavening agents, par baking, proofing, or modified atmospherepackaging.

For instance, metabolized portion in a total dough composition(metabolized portion plus additional ingredients) in an amount in therange from about 10 to about 90 parts metabolized portion based on 100parts total dough composition can be useful.

For a metabolized portion in the form of a pre-fermented sponge, it maybe useful to include nearly any relative amount of the pre fermentedsponge. For example, without identifying any limit with respect to theinvention, useful relative amounts of a pre-fermented sponge per totaldough composition may be from about 25 to about 80 parts by weightpre-fermented sponge per 100 parts total dough composition, e.g., fromabout 45 to about 60 parts by weight sponge.

For a re-work dough composition as the metabolized portion, it may beuseful to include nearly any relative amount. Without identifying anylimit with respect to the invention, useful relative amounts of are-work dough composition per total dough composition may be from about5 to 50 percent.

Flour

Suitable flour for the dough composition can be flour as described abovewith respect to the sponge or re-work, or any other flour. The addedflour may be the same or different from the flour included in themetabolized portion. Many flours are generally known, useful, orcommercially available, with high protein flours being preferred.

The amount of flour added to the metabolized portion to produce thedough composition can be enough such that the total flour in the doughcomposition can be effective to provide desired structure andconsistency to the dough composition. The total amount of flour in thedough composition should not be so high to cause the dough compositionto be dry or weak, i.e., have little extensibility and therefore reducedability to expand. A dough composition can, for example, include flourin an amount of between about 30 weight percent and about 55 weightpercent, preferably between about 35 weight percent and about 50 weightpercent, and more preferably between about 40 weight percent and about45 weight percent.

These amount of total flour in a dough composition are based on flourhaving about 13 weight percent to about 15 weight percent moisture,about 12 weight percent to about 14 weight percent wheat protein, andabout 0.4 weight percent to about 0.6 weight percent ash based on theamount of flour. One skilled in the art having read this descriptionwill readily understand that flour amounts suitable for use with a doughcomposition can vary on a variety of factors including, for example, thecharacteristics of flour used and the desired properties of the doughcomposition and the baked dough product.

Water

The amount of water added to the metabolized portion can be enough toprovide the final dough composition with an amount of water that iseffective to provide a desirable dough composition consistency.

Water can act as a plasticizer, a leavening agent, or both. When wateracts as a plasticizer, water provides the dough composition withextensibility. Desirable extensibility facilitates baking the doughcomposition into a product having a desirable baked specific volume.Moreover, water can facilitate the leavening of the dough composition byforming steam, which acts to expand the dough.

The amount of water from all sources, for example, water, eggs, milk,etc., should not be so high that the dough composition becomes so softthat it cannot maintain a desired structure, especially a closed-ellstructure comprising a developed matrix containing bubbles of carbondioxide and water vapor. On the other hand, the amount of water shouldnot be so low that the dough composition is dry has no ability toexpand, i.e., extensibility.

Strengthener

A strengthener, e.g., a protein supplement such as glutentransglutaminase, or another strengthener, can be included in a doughcomposition to provide desired structure and strength. A strengthenercan contribute to a baked product prepared from a dough composition, acrisp, brown outer crust as well as a tender interior that is moist butnot doughy. Strengtheners such as protein supplements that provide thesecharacteristics are generally known.

In general, strengtheners can react protein ingredients in a doughcomposition to provide improved viscoelasticity. This strengthens anddevelops a dough composition, allowing expansion of the doughcomposition during processing and allowing the dough composition tomaintain bubbles. Additionally, a strengthener can strengthen or developa dough composition, e.g., dough composition matrix, to providestability and mechanical durability of the matrix during freezing andallowing bubbles to be maintained through frozen storage, even troughmultiple thaw cycles.

Exemplary suitable protein supplements can include proteins resultingfrom amino acids such as, for example glycine, alanine, leucine,isoleucine, valine, phentolamine, turicine, tryptophan, proline,methionine, cystine, serine, threonine, asparagine, glutamine,histidine, aspartic acid, glutamic acid, lysine, and arginine. Othersuitable protein supplements include, for example, α-keratin, collagen,fibroin, sclerolin, myosin, actin, carboxypeptidase, trypsin, ovalbumin,casein, and the like.

The dough composition may include a dairy protein, an egg protein, awheat protein, or a combination thereof. Examples of suitable dairyproteins include whey, soy protein, caseinate, buttermilk, buttermilksolids, and nonfat dry milk.

Examples of suitable egg proteins include albumin. Examples of suitablewheat proteins include gluten or those derived from flour. The doughcomposition includes a protein supplement in an amount from all sources,for example, eggs, flour, gluten, etc., effective to provide a bakedproduct having a crisp exterior and a moist but nondoughy interior. Thetotal amount of protein supplement in the dough composition should notexceed an amount that would provide a tough, crumbly baked product. Yetthe total amount of protein supplement should not be so low that a doughcomposition provides a baked product having a gummy, doughy texture.

A dough composition can typically include a protein supplement such asgluten in an amount that will provide desired properties as describedherein. Exemplary amounts can be in the range between about 2 weightpercent and about 8 weight percent, preferably between about 3 weightpercent and about 7 weight percent, and more preferably between about 4weight percent and about 6 weight percent based on the total weight ofthe dough.

Other materials that can be used as strengtheners includetransglutaminase, ascorbic acid, diacetyl tartaric acid esters of monoand diglycerides (“datem”), and sodium stearoly lactylate (“SSL”).

Transglutaminase is an enzyme that may be useful in embodiments of theinvention to strengthen dough by connecting proteins. Transglutaminaseis readily available.

Shortening

Shortening must generally be included in the dough composition.Shortening contributes to a baked dough product having desirablepalatability, physical texture, physical form, and overall aestheticappeal. The shortening generally provides a baked product with a tender,soft, flaky mouth feel; a light flaky texture; and a crisp outer crustwith a glossy appearance. Shorting can also act as a plasticizer and cancontribute to the volume and grain of a baked product. Shortening can benatural, for example, animal or vegetable shortening, or synthetic.

Shortens generally include fats and fatty oils, which are made ofpredominantly triesters of glycerol with fatty acids, commonly calledtriglycerides. The number of triglycerides in a given natural it is afunction of the number of fatty acids present and specificity of theenzyme systems involved in that particular fat-synthesis reaction.

Fats and fatty oils useful in producing shortening consistent with theinvention include cottonseed oil, ground nut oil, soybean oil, sunfloweroil, rape seed oil, sesame oil, olive oil, corn oil, safflower oil, palmoil, palm kernel oil, coconut oil, and combinations thereof.

The dough composition can include any number of shorten compositionshaving a variety of physical states and/or physical forms. Suitablephysical states of shortening include liquid, semisolid, and solid.Suitable physical forms of shortening include plasticized shortening,chip shortening, and extruded shortening. Preferably the shortening inthe dough composition includes butter, hydrogenated vegetable oil,hydrogenated soybean oil, or a combination thereof.

The amount of shortening in a dough composition is effective to providea baked product having a tender, soft, fluffy mouth eel; a light, flakytexture; and a crisp outer crust. The amount of shortening should notexceed an amount that would provide a baked product having a gummytexture. Yet the amount of shortening should not be so low that a doughcomposition of the invention provides a baked product having a tough,dry, crumbly texture and a less than desirable specific volume.

Water-Binding Agent

A dough composition of the invention may include a water-binding agent(also referred to as a “freezing temperature reducing agent”).

A freezing-temperature reducing agent or water-binding agent can beadded to either a sponge or a dough composition to reduce the amount ofwater of a dough composition that freezes, keeping more water in thedough composition in a liquid form. Because liquid water absorbsrelatively more carbon dioxide than ice, preventing the water fromfreezing allows more carbon dioxide to be absorbed by the doughcomposition. Thus, the effect of a freezing-point depressant can be toincrease the amount of un-frozen water in the frozen dough composition,thereby increasing the amount of absorbed carbon dioxide.

Any type and amount of freezing-point depressant can be useful as willbe understood by a skilled artisan, and many are commercially available.A preferred example of a freezing point depressant is alcoholsgenerally, including ethanol. The amount can be any amount that willreduce the freezing point of the dough composition, and the exact amountused in any dough composition will depend on a variety of factorsincluding the balance of the ingredients in the dough composition, andthe particular freezing-point depressant being used.

Other water-binding agents suitable for use in a dough composition ofthe invention include gelling agents and thickening agents. A suitablegelling agent includes any compound that can form a gel. Examples ofgelling agents include hydrocolloid gums and gel-forming proteins.Examples of suitable hydrocolloid gums include pectin, alginate,carrageenan, carboxymethyl cellulose, methyl cellulose, hydroxypropylcellulose, hydroxypropylmethyl cellulose, etc.

Examples of suitable gel-forming proteins include gelatin, hydrolyzedgelatin, gelatin precursors such as collagen, etc.

Some gelling agents that have been particularly useful in a doughcomposition of the invention are those packaged with an amylase such as,for example, GENU® FREEZE (Copenhagen Pectin A/S, Denmark) and GENU®FOOD GUM X6021 (Copenhagen Pectin A/S, Denmark). Thus, a doughcomposition of the invention can include an amylase. An amylase includesany enzyme that can hydrolyze O-glucosyl linkages in starch, glycogen,and related polysaccharides. Examples of amylase include α-amylase.

The amount of water-binding agent in a dough composition is effective toprovide desirable baking development and desirable frozen stability. Theamount of water-binding agent should not exceed an amount that wouldresult in a dough composition that is so dry that it loses its abilityto expand. Yet the amount of water-binding agent should not be so lowthat the amount of water absorbed into the dough composition is sonegligible that a desirable baked product cannot be prepared, or, in thecase of a laminated product, becomes so soft that its dough layers mergewith shortening layers.

The amount of such water-binding agent can be in a range of betweenabout 0.2 weight percent and about 1 weight percent, preferably betweenabout 0.5 weight percent and about 0.9 weight percent, and morepreferably between about 0.6 weight percent and about 0.8 weight percentbased on the total weight of dough composition. Moreover, a doughcomposition of the invention typically includes a ratio of water-bindingagent to water of between about 0.005:1 and about 0.05:1, preferablybetween about 0.015:1 and about 0.025:1, and more preferably betweenabout 0.01:1 and about 0.03:1.

Non-Metabolically Active Yeast

A dough composition of the invention includes non-metabolically activeyeast to, during baking, metabolize and increase the volume, and alterthe texture of a baked product prepared from dough composition.

The amount of a non-metabolically active yeast, when considered withother leavening agents in the dough composition such as carbon dioxide,bubbles, air, steam, etc., cause leavening of a dough composition duringbaking. A non-metabolically active yeast can be present in the doughcomposition in an amount of between about 0.5 weight percent and about 6weight percent, preferably between about 0.75 weight percent and about 5weight percent, and more preferably between about 3 weight percent andabout 4 weight percent based on the total weight of the dough. In oneembodiment, approximately ⅓ metabolically active yeast and 213non-metabolically active yeasts are used (i.e. 2% active and 4%non-active).

Other Additional Ingredients

Dough compositions also typically include sugar and salt. Salt canenhance the flavor of a baked product prepared from a dough compositionof the invention, impart toughness to the gluten, and provide strengthto the crumb. Salt can be present in an amount effective to provide adesirable flavor. Salt is typically present in a range of between about0.3 weight percent and about 1 weight percent.

Sugar can also enhance the flavor of a baked product prepared from adough composition of the invention. Sugar acts as a substrate for yeastand as a starting material for the Maillard reaction, which facilitatescolor formation of the crust. Sugar is typically present in a range ofbetween about 1 weight percent and about 6 weight percent of the totaldough composition. Suitable sugars include granulated sugar, honey, highfructose corn syrup, etc.

The dough composition of the invention can also include other additives,for example, emulsifiers, dough-developing agents, nutritionalsupplements, flavorings, shelf-life stabilizers, thickeners, organicacids, oxidizers, and the like. Additives can modify texture or anynumber of characteristics of a dough composition of the invention or abaked product resulting therefrom.

An emulsifier can influence the texture and homogeneity of the doughcomposition mixture, increase dough composition stability, and improvethe eating quality of a baked product. An emulsifier includes nonionicsurfactants, anionic surfactants, and cationic surfactants. Suitableembers include, for example, lecithin, mono- and diglycerides of fattyacids, propylene glycol monoesters and diesters of fatty acids,glyceryl-lacto esters of fatty acids, ethoxylated monoglycerides anddiglycerides, sodium stearoyl lactylate, etc.

Exemplary Dough ingredients WEIGHT PERCENT MORE INGREDIENT USEFULPREFERRED PREFERRED Flour 30-55 35-50 40-45 Strengthener (e.g., 2-8 3-74-6 gluten) Shortening  3-10 5-9 6-8 Water 25-35 26-41 27-30Water-binding agent 0.2-1   0.5-0.9 0.6-0.8 Yeast (total) 0.5-6  0.75-5   3-4 Non-metabolically active 1-6 2-5 3-4 yeast Metabolicallyactive 0-3 0.5-2.5 1-2 yeast

A dough composition of the invention can optionally be free of relaxingagents that facilitate a dough's resistance to mechanical stresses suchas mixing, sheeting, etc. Relaxing agents can adversely affect the shelflife of frozen doughs as well as specific volume. The term “free of” asused herein includes an amount of less Man 20 ppm, preferably no morethan 15 ppm, and more preferably no more than 10 ppm based on flour.Relaxing agents can include reducing agents such as, for example,cysteine, bisulfate, sorbate, etc. In one embodiment, a doughcomposition of the invention is free of cysteine. A dough composition ofthe invention can also be free of a modified starch (e.g., cross-linkedstarches derived from maize or tapioca).

Dough compositions of the invention can be un-proofed, non-par baked,freezer-to-oven, yeast-leavened dough compositions. These doughcompositions can be baked to baked specific volumes that are typical andconventional in the baking industry of useful yeast leavened doughproducts, including pre-proofed or thawed-and-proofed yeast-leaveneddough products. For example, the dough compositions of the invention canbe baked from frozen to produce a baked dough product having a bakedspecific volume of at least 2 cubic centimeters per gram (cc/g).

Considered differently, the dough compositions of the invention, asdescribed herein to be prepared from a metabolized portion (e.g., spongeor re-work), and other described ingredients and processing steps, canbe baked to a baked dough product that is substantially of the samequality and preferably of an improved quality, as compared toconventional baked dough products that use standard methods and nometabolized portion as discussed herein. For example, a baked doughproduct of the invention may exhibit a baked specific volume that isfrom about 50 to about 100 percent greater in baked specific volumecompared to a baked product prepared from a dough composition of thesame ingredients but with no pre-fermenting of a sponge, or including nore-work, or even including the use of a sponge or rework but indifferent amounts or using different (standard) processing techniques.

The act baked specific volume of any particular dough product of theinvention can depend on the type of dough product, the use of selectedprocessing steps as described herein, relative amounts of ingredients,and the exact dough formulation. Exemplar baked specific volumes ofdough product prepared according to the invention, e.g., using ametabolized portion such as a pre-fermented sponge or re-work doughcomposition, can preferably be at least about 2.5 cc/g, preferably atleast about 3 cc/g, even up to about 5.5 or 6 cc/g. The baked specificvolume of a baked dough product will depend greatly on the compositionof the dough composition and the type of dough product it is composed toproduce, e.g., a bread loaf, a roll, a sweet roil, a pizza crust,Danish, etc. The methods and compositions of the invention can result inimproved baked specific volumes for all of these and other types ofdough products.

Processing a Metabolized Portion into a Dough Composition

A metabolized portion can be combined with additional dough ingredientsby any useful methods, as will be understood, based on this description,by one of sill in the arts of dough compositions and processing. Themetabolized portion can generally be combined with additional doughingredients in any manner that allows the production of a doughcomposition. Conventional and known methods of preparing dough productswill be useful, such as by mixing.

According to the invention, the metabolized portion can be combined withadditional dough ingredients in a manner and under conditions that allowthe gluten-stabilized bubbles of the metabolized portion to beeffectively maintained in the final dough composition. The bubbles thatare transferred from the metabolized portion to the final doughcomposition are preferably retained in the dough composition to laterserve as nucleation sites for gases (e.g., carbon dioxide, water vapor)to cause expansion of the dough, without the need for proofing, in asubsequent baking step.

The metabolized portion can be combined with the additional doughingredients as necessary or useful, and as appropriate, depending on thetype and composition of the metabolized portion. If the metabolizedportion is a sponge as discussed according to one embodiment of theinvention, the sponge can be first prepared and then the additionalingredients (separately or together) can be incorporated into the spongeto make a final dough composition having the composition of the combinedsponge and additional ingredients. If the metabolized portion is are-work dough composition, as discussed as another embodiment, there-work portion is removed from a dough composition that is essentiallya complete dough composition. After the re-work is removed from thatdough composition, the re-work is combined with “additional doughingredients,” i.e., the dough composition from which the re-work wasremoved, but upstream from where removal occurred, to prepare a finaldough composition having the same composition as the original doughcomposition from which the re-work was removed, and also the samecomposition as the re-work. According to the invention, the combinedfinally-processed dough composition will retain bubbles andmetabolically active yeast from the metabolized portion, andnon-metabolically active yeast from the added dough ingredients or doughcomposition.

In preferred embodiments, a dough composition can be prepared bycombining a metabolized portion (e.g., a pre-fermented sponge or rework)with additional dough ingredients, and mixing until the doughcomposition is fully developed. “Fully developed” refers to transformingthe mixture into a cohesive mass such that the dough composition issubstantially homogenous and soft.

As described, the metabolized portion of dough contains activelyfermenting or metabolically active yeast and therefore metabolites suchas carbon dioxide and ethanol. It is possible, and in some embodimentsof the invention preferable, for the actively-fermenting yeast of themetabolized portion to continue evolving metabolites, e.g., carbondioxide, into later processing steps of combining the metabolizedportion with other dough ingredients, and through a portion of cooling,processing, folding, lapping, cutting, and freezing, thereby addingadditional carbon dioxide and larger bubbles to the dough composition.In general, the larger the initial RSV, the larger the final bakedspecific volume (“BSV”) upon baking. Generally, a dough product having aBSV of between about 1.2 and 1.5 is preferred.

The BSV of a product relates the volume of the baked product to theweight of the product. Generally, products with higher BSVs are lighterand have more gas or air incorporated into the product. Products withlower BSVs are heavy, dense and generally are undesirable in developeddoughs.

BSV can be measured using commonplace displacement methods. One exampleof a method commonly used is the rapeseed method. In this method, abaked product of a known mass is placed in a container coining a knownand measurable volume of rapeseed. Once the baked product is placed inthe container containing the baked product, the volume of the rapeseedand baked product is measured. The specific volume of the baked productis then determined by dividing the volume of the baked product by themass of the baked product.

Generally, BSV is reported in ml/g developed dough products such asbaked breads and rolls generally have BSVs of from about 4 ml/g to 7ml/g. Dough products, such as baked breads and rolls generally haveimproved BSVs. Improved BSVs can refer to higher values of BSV orsimilar values of BSV obtained with a shorter mixing time for the dough.In one embodiment, methods of the invention provide baked goods withBSVs similar to doughs t were mixed for a longer period of time.

Equipment useful for mixing the metabolized portion and additional doughingredients will be readily understood, and is commercially available.An example of a suitable mixer includes a vertical mixer (Hobart Troy,Ohio). During mixing, the dough composition of the can desirably bemaintained at a temperature that maintains the structure of the doughcomposition to facilitate handling. Typically the temperature should bein a range of between about 60° F. and about 70° F., preferably betweenabout 62° F. and about 68° F., and more preferably between about 64° F.and about 66° F. Preferably the mixer can be equipped with arefrigeration system such as, for example, a jacketed glycol coolant tomaintain the dough composition of the invention within the desirabletemperature range.

To maintain the desirable temperature, the water added can be at atemperature suitable for maintaining the dough composition at thedesirable temperature. Preferably the water is at a temperature ofbetween about 60° F. and about 65° F. To bring the water to atemperature suitable for maintaining the dough composition at thedesirable temperature, a portion of the water can be replaced by shavedor crushed ice. The amount and size of the shaved or crushed ice can bedetermined so that the ice can melt in the water, the dough, or bothduring mixing without leaving ice in the mixed dough. If ice remains inthe mixed dough, wet spots will appear in the dough, which isundesirable. The size of the shaved or crushed ice can typically be upto about 1 cm. The portion of water that is replaced by shaved ice canbe up to about 50 weight percent of total water.

The dough composition can be mixed at a speed and time suitable forfully developing the dough. For example, the ingredients can initiallybe mixed on low speed for about 30 seconds and then mixed on mediumspeed for between about 8 minutes and about 12 minutes. These times andspeeds are merely illustrative and can vary depending on the amount ofdough composition being mixed and on the type of mixer.

After mixing, a dough composition desirably has a temperature of betweenabout 60° F. and about 70° F., preferably between about 62° F. and about68° F., and more preferably between about 64° F. and about 66° F.

Processing

Once the dough composition has been prepared, it can be furtherprocessed according to known methods of forming a dough composition intoa desired size and shape (followed by other processing steps such aspackaging freezing, and cooling). A variety of techniques can be usedfor processing. For example, processing of the dough composition caninclude one or more of sheeting exuding, dividing and rounding, and thelike; cutting to a desired size and shape; folding; filling; andcooking. According to the invention, any processing can be useful,including any one or more of those identified directly above. Preferredprocessing techniques can include sheeting, dividing and rounding, orany other technique that results in a processed dough composition thatcontains bubbles, metabolically active yeast, and non-metabolicallyactive yeast, to provide freezer-to-oven capabilities as describedherein.

As mentioned herein, processing of a dough composition according to theinvention can also include removal of dough composition, in-process, asre-work, for re-introduction into the processing at an upstream step.This is specifically useful in the “re-work” embodiment, but can also beuseful in the “sponge” embodiment, or other embodiments that will makeuse of the overall inventive concepts described herein.

The sheeted or divided and rounded dough composition can be assembledinto any of a variety of shapes and products, as desired. Methods andequipment for shaping, sizing, or otherwise cutting sheeted doughcompositions are well known.

The size and shape of the dough product may depend on the type of doughproduct being prepared, as well as other factors such as the doughcomposition, e.g., whether it is light and/or sweet like a donut orheavy like a pretzel or bagel, whether or not it is intended to beheated (e.g., in a toaster), etc.

In one embodiment of the invention, the dough product can be cut androlled into the form of a Danish, which can be formed by cutting a stripof dough composition, adding flavoring to a surface, and roiling from anend. Another embodiment provides for shaping the dough composition intoa pizza crust.

Methods of shaping and so a dough product, including steps of sheeting,cutting, folding, perforating, crimping, and other wise assembling, arewell known, and are described, for example, in Assignee's copending U.S.patent application Ser. No. 09/432,446, filed Nov. 3, 1999, incorporatedherein by reference.

Certain embodiments of inventive dough compositions, e.g., Danishes orcroissants, can be processed and assembled into a laminated doughproduct, using methods more generally known in the dough products art,by processing the dough composition using a laminating or lapping step.Such laminated dough products generally include shortening layersaltering with dough layers, produced by lapping. Exemplary laminatedproducts and lamination processing steps are described, for example, inAssignee's U.S. Pat. No. 6,579,554 entitled “Freezer-to-Oven Laminated,Unproofed Dough and Products Resulting Therefrom,” filed Apr. 14, 2000,the entire disclosure being incorporated herein by reference.

Generally, processing to a laminated product can be accomplished bytaking a dough composition and rolling in shortening layers. Rolling inshortening can be performed by known methods, and generally involvesincorporating and maintaining layers of shortening between adjacentlayers of dough composition. The dough composition and shortening areseparately prepared. Shortening can be rolled into the dough compositionby first wrapping a slab of shortening with the dough composition andthen sheeting to prepare a sheet of layered dough and shortening. Thesheet cm be repeatedly folded and sheeted to provide a laminated doughhaving multiple adjacent layers of shortening and dough composition.

Shortening in the shortening layers can include any solid shortening,which can be natural or synthetic as described above. Preferably theshortening in the shortening layers includes butter.

According to the invention, when processing by lapping to produce alaminated dough product, the lapping step can also provide an amount ofentrapped gas for leavening during baking. Thus, the metabolized portionof the dough composition need not contain as high of a concentration ofbubbles or gas as when producing non-laminated dough products.Therefore, in preparing a laminated dough product, it can be preferredto use a metabolized portion of dough (e.g., re-mix or sponge) having arelatively low amount of gas or bubbles, so that the bubbles do notinterfere with lapping and disrupt the laminated layers.

By different embodiments of the invention will be understood by those ofskill in the dough products and dough processing arts. As one specificexample, this specification describes the preparation of a pre-fermentedsponge and combination of that sponge with additional ingredientsincluding non-metabolized yeast, to produce a frozen dough compositionthat can be baked from frozen, without proofing or par-baking, andwithout the need for modified atmosphere packaging. As another example,the present specification describes a similar process that uses reworkdough in place of the pre-fermented sponge. The re-work contains carbondioxide bubbles and developed dough mat, as does the sponge, andtherefore provides a useful metabolized dough portion.

Other additional processing steps and techniques, as will be understoodby those of skill based on the overall disclosure herein, arecontemplated to be used in combination with the specifically-describedconcepts identified. As an example, it will be apparent that the methodsdescribed herein for preparing dough compositions will be useful incombination with continuous dough processing techniques. The sponge orre-work embodiments each allow for continuous processing of a doughcomposition, including continuous preparation and further processing offermented sponge, or continuous re-working of any dough compositionprepared by a sponge method or otherwise. In particular, the inventioncontemplates the use of a sponge dough method to initialize a continuousdough production method, and thereafter, once steady-state processing isachieved, eliminating the use of pre-fermented sponge and replacing themetabolized portion in the form of a pre-fermented sponge with ametabolized portion in the form of re-work dough removed from adownstream section of the processing line (e.g., a cutting section) andre-introduced into the process upstream, e.g., at the stage. The mixingstage can be preferred for re-introduction of rework, becausere-introduction of re-mix at the mixing stage allows bubbles from there-mix to be incorporated into and maintained in the resultant combinedmixed dough composition.

Shaping/Forming the Dough Composition

The processed dough composition can be formed into any desirable shape,such as the shapes typically used for a desired dough product, e.g., acroissant, Danish, loaf, pizza crust, roll, etc. The formed doughcomposition can be transferred to any container suitable for freezing.The dough composition can be shaped as desired, or otherwise processedusing known methods and equipment. For example, the dough compositionmay be processed by any combination of layer extruding, rolling,folding, cutting, combing with other dough materials or fillings,layered with additional shortening, frosted, or processed in any otherfashion to form any of a countless variety of dough products for baking.One skilled in the art having read the specification would understandthat the mixing and rolling steps are generally performed using goodpuffed-pastry technique.

A dough composition of the invention is particularly desirable becauseit can pare a baked dough product that has a specific volume of at least3 cc/g, preferably between about 4 cc/g and about 6 cc/g, and morepreferably between about 4.5 cc/g and about 5.5 cc/g, withoutpre-proofing, and without the need for chemical leavening agents.

One advantage of a dough composition of the invention is that it doesnot need to be proofed or thawed prior to baking, which is useful forsaving time and storage space.

Another advantage of a dough composition of the invention is that thedough composition is more resilient to temperature fluctuations so thatit can maintain its stability and integrity, through freezing andthawing. This is a result, at least in part, of the developed doughmatrix.

Another advantage of a dough composition of the invention is that thedough composition does not need to be packaged under a modifiedatmosphere.

In one embodiment of the invention, a coating or glaze may be placed onthe dough, e.g., after forming, to minimize the loss of gaseous carbondioxide from frozen dough composition over shelf life time. Such acoating is optional, and is not required according to the invention tomaintain an amount of carbon dioxide in the dough composition. Thecoating should be suitable for a food product, and may be any materialthat acts as a barrier to gaseous carbon dioxide. An example of asuitable coating can be a thin vainer of ice. Another example of asuitable barrier is a guar wash, which can be an aqueous solutioncontain guar.

Freezing and Packaging

After a dough composition is formed into a desired shape and placed intoa container, the dough composition can be frozen to a temperaturesuitable for shipping and storage. A dough composition can preferably befrozen as quickly and completely as possible. A dough compositionprepared as described herein can be frozen and stored frozen for up toabout two months, preferably up to about four months, and morepreferably up to about six months. Temperatures suitable for freezing adough composition of the invention include, for example, less than about30° F., preferably less than about 10° F., and more preferably less thanabout −10° F.

The dough composition can be packaged by any desired methods and usingany desired packaging materials. The packaging need not be air tight,but can preferably be closed to prevent water loss. The doughcomposition can be shelf stable without storage in a package thatcontains a modified atmosphere such as, for example, without storage inconcentrated carbon dioxide, nitrogen, or with limited head space. Suchmodified atmosphere packaging can be used if desired. “Shelf stable”refers to the dough composition of the invention being suitable forstorage at freezing temperatures without the dough compositionsubstantially breaking down by, for example, by microbial contamination,water accumulation, failure of the leavening agent, etc. and becomingunsuitable for consumption.

Baking Step

For baking, the oven can be cold or preheated. The baking temperatureand time can depend on, for example, the size and shape of the doughcomposition as well as whether the oven is cold or preheated. Thetemperature of the oven can be in a range of, for example, between about365° F. and about 400° F., preferably between about 370° F. and about380° F., and more preferably between about 375° F. and 377° F. The doughcomposition can be baked at is temperature for between about 22 minutesand about 32 minutes, preferably between about 24 minutes and about 30minutes, and more preferably between about 25 minutes and about 27minutes.

While not wishing to be bound by theory, it is believed that the yeastof the dough composition have limited time or opportunity to evolvecarbon dioxide during the baking cycle. As described earlier, themetabolically active yeast in the sponge contribute carbon dioxide tothe dough composition prior to during the preferment process. Uponfreezing, the solubility of the carbon dioxide increases significantly,effectively increasing the concentration of carbon dioxide in theunfrozen water portion of the dough. Upon baking, the solubility of thecarbon dioxide decreases and gaseous carbon dioxide is released into thedough, and expands to result in an increase in the specific volume ofthe baked dough product. Also contributing to leavening during bakingwill be the amount of non-metabolically active yeast in the doughcomposition.

One skilled in the art would understand the baking time and temperaturemay vary depending on the extent the dough composition is thawed.

EXAMPLES Materials & Methods: Dinner Roll

Dough composition prepared as follows:

Formula 1 = 4& Batees (2% lpf) % Protein (FB)): 26.505 FLOUR/WATER:BATCH WT (GMS): 2500

CHEMIST INGREDIENT [%] WT (GMS) Hard Flour, BL 47.04 1176 WATER 30.06751.5 Gluten 6.00 150 Dough composition 0.40 10 Conditioner Salt 1.00 25Butter 4.00 100 Glycerol 1.50 37.5 Preferment Dextrose 2.00 50Compressed yeas 6.00 150 Sucrose 2.00 50 DOUGH 100.00 2500 COMPOSITIONTOTAL %

Dough composition WT Conditioner Preblend % Dough (GMS) DATEM w/amylas0.175 4.375 Ascorbic Acid 0.005 0.125 Azodicarbonamide 0.02 0.5 SSL 0.25

Procedures:

1)-Liquid preferment: Combine preferment ingredients and let stand atroom temp. for 60 minutes.

Ingred. (gm) water 596.75 flour 615.17 yeast 61.54 dextrose 50 TOTAL1323.5

2) Combine formula minors, flour, glycerol, and ice with liquidpreferment in a cold mixing bowl.

Ingred. (gm) Prefer. 1323.5 preferment above flour 560.83 yeast 88.46ice 154.75 glycerol 37.5 dextrose 0 minors 235 remaining ingredientsminus butter TOTAL 2400

3) Mix at spd #1 for 60 sec, add butter (see step 2 below), mix at spd#1 for 60 sec, mix spd #2 for 8 minutesPeak BU's are 900 (+/−100)

(gm) Step 2 2400 dough composition minus butter Butter 100 TOTAL 2500

4) Form into 100 gm dinner rolls; freeze and store rolls @ −10 F.

5) Bake frozen dinner rolls @ 375° F. for 35 minutes.

Example

1. Sheet approximately 400 gm dough composition (described in DinnerRoll example) to 4 mm on a Rondo sheeter Model Nr. STM 513).

2. Using a 6″ diameter pan as a guide, cut out a circular piece of doughcomposition (weight of dough composition=175-200 gm).

3. Spray 6″ pan with Vegalene (non-stick spray) prior to depositing anddocking the dough.

4. Place dough/pan into a −10° F. freezer.

Sample 2

1. Sheet a 400 gm piece of dough composition to 2 mm.

2. Using a 6″ diameter pan as a guide, cut out two circular pieces ofdough composition (100 gm each).

3. Spray 6″ pans with Vegalene (non-stick spray) prior to depositing anddocking the dough composition samples.

4. Place both samples into a −10° F. freezer.

After 24 hours at −10° F., the pizza crust samples described above weretopped with approximately 30-40 gm pizza sauce plus 50 gm mozzarellacheese. The samples were biked in a conventional oven at 425° F. for20-25 minutes.

Data & Observations:

The pizza samples successfully leavened upon baking directly from thefrozen state in 6″ personal pan pizza baking pans. Crust was toast brownin color and possessed a tender texture.

The following examples are based on a Danish, one havingtransglutaminase and one without.

FTO Danish Ingredient Percent % Enzyme added Yeast 4 Sucrose 3.67 Water23.6 Promax 44.37 Victory 3 Ice 0.73 Eggs 6 Salt 0.731 Gluten 3 Butter 3Replacer 2 Mongly 1 SSL 0.25 Veron 0.005 Transglutaminase AA 0.003 Salp0.34 Soda 0.34 TOTAL 100.00 Roll-in 15Coffee cake topping:Butter, unsalted 24.6%

Cinnamon 2.2% Salt 0.5% Vanilla 0.2%

Step 1) Combine ingredients and mix smooth at low speedGranulated sugar 43%

Promax 29.5%

Step 2) Add sugar and flour and mix at low speed until mixture becomescrumblyUse cinnamon filling. Make filling 12-15% weight of dough.Spread on uniformly, leaving top 1 inch border clean of filling rollcoated dough pad into a log and cut to desired length.Danish multipack: Apple filled pockets and cream cheese filled pockets;sweet rolls containing almond paste, snails topped with Bavarian crème.

This example shows the reworked product but without transglutaminase:BSV 2.4, which is not as high as samples containing transglutaminase.

FTO Danish with salp and soda added to addition of chem leavening.

Time 0 BSV=2.44

Accelerated shelf life=2.42

Ingredients % dough Victory Flour 41.24 Rework 12 Liquid egg 5.96 Ice5.81 Water 13.29 butter 34 3.28 Yeast 2.98 Sugar 5.36 Gluten 4.5 NFDM(skim) 2.38 Mono/dig 1.07 Salt 0.66 Vanilla liquid 0.6 Cardamon 0.18Ascorbic acid 0.01 low salp 0.34 Soda 0.34 100% Lam. Butter 16.43Add all ingredients (except for butter, chem leaveners and yeast). Mixfor 5 minutesAdd mix butter and leavening and mix for 5 minutes.Target dough temp=15 C36 layers with rest on conveyor

no chem Ingredients % dough (decrease salt by 30%) Victory Flour 40.2440.57 41.08 40.4 Rework 12 12 12 12 Liquid egg 5.96 5.96 5.96 5.96 Ice5.81 5.81 5.81 5.81 Water 13.29 13.29 13.29 13.29 butter 34 3.28 3.283.28 3.28 Yeast 3.98 3.98 3.98 3.98 Sugar 5.36 5.36 5.36 5.36 Gluten 4.54.5 4.5 4.5 NFDM (skim) 2.38 2.38 2.38 2.38 Mono/dig 1.07 1.07 1.07 1.07Salt 0.66 0.33 0.5 0.5 Vanilla liquid 0.6 0.6 0.6 0.6 Cardamon 0.18 0.180.18 0.18 Ascorbic acid 0.01 0.01 0.01 0.01 low salp 0.34 0.34 0.34 Soda0.34 0.34 0.34 100% 100% 100% 100% Lam. Butter 16.43 16.43 16.43 16.43

It will thus be seen according to the present invention a highlyadvantageous freezer to over dough has been provided. While theinvention has been described in connection with what is presentlyconsidered to be the most practical and preferred embodiment, it will beapparent to those of ordinary skill in the art that the invention is notto be limited to the disclosed embodiment, that many modifications andequivalent arrangements may be made thereof within the scope of theinvention, which scope is to be accorded the broadest interpretation ofthe amended claims so as to encompass all equivalent structures andproducts.

The inventors hereby state their intent to rely on the Dine ofEquivalents to determine and assess the reasonably fair scope of theirinvention as it pertains to any apparatus, system, method or article notmaterially dept from but outside the literal scope of the invention asset out in the following claims.

1-13. (canceled)
 14. A method of making a laminated dough composition,the method comprising providing a dough composition comprising water,flour, yeast, and transglutaminase, and processing the dough compositionby lapping the dough composition to form multiple layers of doughcomposition and shortening to provide a developed dough matrix.
 15. Themethod of claim 14, wherein the dough composition is unproofed and canbe frozen, and then baked without thawing to produce a yeast-leavened,baked dough product.
 16. The method of claim 14, wherein the doughcomposition is a frozen, unproofed dough composition.
 17. The method ofclaim 14, wherein the dough composition can be baked to a baked specificvolume of at least 2.5 cubic centimeters per gram. 18-21. (canceled) 22.A laminated dough composition comprising alternating dough compositionlayers and shortening layers, wherein the dough composition layersinclude transglutaminase.
 23. (canceled)
 24. A dough composition madeaccording to a method of preparing an unproofed dough compositioncapable of being frozen and baked without thawing to create ayeast-leavened baked dough product, the method comprising providing aset of ingredients including at least yeast, water, and flour, combiningand processing the ingredients in combination with additional doughingredients to produce a dough composition, the combining and processingincluding allowing a portion of the yeast to actively ferment a portionof the ingredients; developing the dough composition, generating bubblesin the developed dough composition, and providing non-metabolicallyactive yeast in the developed dough composition; wherein the combinationof bubbles, developed dough composition, and non-metabolically activeyeast, results in an unproofed dough composition capable of being frozenwithout partially baking, and baked without thawing, to create ayeast-leavened baked dough product.
 25. The dough composition of claim24, wherein the dough composition is frozen, and packaged in anon-modified atmosphere package.
 26. A dough composition made accordingto a method of making an unproofed dough composition, the methodcomprising: providing a metabolized dough portion comprisingmetabolically-active yeast, bubbles, and developed dough matrix, andcombining the metabolized dough portion with additional doughingredients including non-metabolically active yeast, to form a doughcomposition that contains bubbles in developed dough matrix, and thatcontains non-metabolically active yeast, wherein the unproofed doughcomposition can be frozen and baked without thawing or proofing toproduce a yeast-leavened baked dough product.
 27. A dough compositionmade according to a method of making a laminated dough composition, themethod comprising: providing a dough composition comprising water,flour, yeast, and transglutaminase; and processing the dough compositionby lapping the dough composition to form multiple layers of doughcomposition and shortening to provide a developed dough matrix.